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|Section2= |Section3= }} Chlorine perchlorate is the chemical compound with the formula Cl2O4. This chlorine oxide is an asymmetric oxide, with one chlorine atom in oxidation state +1 and the other +7, with proper formula ClOClO3. It is produced by the photolysis of chlorine dioxide at room temperature with 436 nm ultraviolet light: :2 ClO2 → ClOClO3 Chlorine perchlorate can also be made the following reactions at −45 °C. :CsClO4 + ClOSO2F → Cs(SO3)F + ClOClO3 Chlorine perchlorate is a pale greenish liquid which decomposes at room temperature. ==Properties== It is less stable than ClO2 and decomposes to O2, Cl2 and Cl2O6 at room temperature. :2 ClOClO3 → O2 + Cl2 + Cl2O6 Chlorine perchlorate reacts with metal chlorides forming anhydrous perchlorates: :CrO2Cl2 + 2 ClOClO3 → 2 Cl2 + CrO2(ClO4)2 :TiCl4 + 4 ClOClO3 → 4 Cl2 + Ti(ClO4)4 抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)』 ■ウィキペディアで「Chlorine perchlorate」の詳細全文を読む スポンサード リンク
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